参脉注射液的HPLC/MS/MS分析

l Re/Rg1;2 Ra1/Ra2;3 Rf/Rbl;4 Ro; 5 Re:6 notoginsenoside Rz;7 Rb2; 8Rb3/Rg2；9 Rhl/Rg2 iso/  malonyl - Rh1 iso.;10 Rhi iso；ll malonyl- Rb2/Rb3/Re; 12Rd；13 Rb2/Rb3/Re iso   /malonyl -Rb2／Rb3/  Re; 14 malonyl- Rd/iso.15 not reported; 16 Rg2 iso  /malonyl- Rd iso; 17 not reponed; 18 not reported;19 Rg6 iso；20 Rg6 iso；21 not reported; 22 F4/R&6; 23 Rk3/Rh4; 24 Rk3/Rh4；25 20 (R) Rg3; 26 20  (S)Rg3; 27 not detected; 28 Rkl/Rg5；29 Rkl/Rg5

色谱柱：HypensilC18柱(250mm×4.6mm,5μm)

流动相：A(CH3COOH-H20-CH3CN,0.01:20:80)-B(CH3COOH-Hz0,0.01:100),B相浓度梯度：开始，70%；lO.Omin,60%;15.Onun,60%;25.Omin,54%;65.Omin,35%;75.Omin,25%;
 85.Onun，stop。

流 速：0.5ml/min

检测波长：202nm

柱 温：40℃